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safe handling and storage of styrene monomer

January 5th, 2021 by

At this conce ntration, 1 cc of the concentrate will raise the level of inhibitor 1 ppm in a drum of styrene having a net weight of 410 pounds. However, fixed-foam protection using an application rate of 0.1 gallons per minute per square surface is recommended. Carbon Dioxide (CO2) Safety, SAFETY DATA SHEET INSTANT HAND SANITIZER GEL / SANTI-GEL, SAFETY DATA SHEET Glen-Pak TM DNA purification cartridge (for use with disposable syringes) 60-5200-xx, EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours), SAFETY DATA SHEET TIDYFOAM E2 HAND CLEANER SANITIZER, Dispelling the Myths of Heat Transfer Fluids. First developed in 1928, styr ene is today one of the mo st important monomers produced by the chemical industry. 2. All sharp ed ges and high points should be ground smooth and rounded to a minimum radius of 1/8. For large fires, water spray or fog may be effective. 9. Chicago, IL Amercoat 346 Ameron Protective Coatings Division 201 North Berry St. Brea, CA Other equivalent or comparable coatings are undoubtedly available and may be equally satisfactory, but it would be advisable to check their resistance characteristics and obtain information on their pe rformance for this application from the m anufacturer before use. Styrene polymerization is initiated by heat, lack of inhibitor and dissolved oxygen, and contact with peroxides and other free-radical initiators, ionic initiators, and redox initiators. T andem seals with barrier fluid are recommended. PRODUCT DATA SHEET Section 1. Department of Environmental Health & Safety Procedures Compressed Gas Cylinder Program March 2010 Compressed Gas Cylinder Program Page 1 of 8 Table of Contents I. Operators wearing rubber-soled shoes, particularly on certain composition floors made of good insulating materials, may pick up considerable static electricity. Roof and sidewall openings above the normal liquid levels in the tank should be of larg e diameter and the number kept to a minimum. does it, amend or replace the Material Safety Data Sheet for Styrene (MSDS. Storage and Handling of Flammable and Combustible Liquids. They should be fitted with closed impellers and mechanical seals. SOLVENT CLEANER MSDS Page 1 of 5 SAFETY DATA SHEET. Additional accidental release, fire an d health information is presented in a su bsequent section of this brochure. 3. 5, 2013) Date of issue:04/07/2018 Revision date: 04/07/2018 IN0001_P Version: 1.0 05/07/2018 EN (English) 1/8 SECTION 1: Identification 1.1. (See Table 2B of this section) Additional inhibitor should be ad ded to maintain a safe level. Violent polymerization … C) x 10-4 at 30 C x 10-4 at 40 C Density, (in air) Temp. BEFORE USING THE UNIT READ THESE INSTRUCTIONS FULLY AND RETAIN THEM FOR FUTURE REFERENCE, To make this website work, we log user data and share it with processors. Table 3B lists the amount of concentrate required to increase the bulk quantity by 1 p pm. The care that must be taken whenever and wherever styrene is used, handled, stored and transported. 4. DOWEX Resins as Organic Solvent Desiccants, SAFETY DATA SHEET. In this experiment, we will use three properties to identify a liquid substance: solubility, density and boiling point.. RULE 1102. Policy Scope, SOLVENT CLEANER MSDS Page 1 of 5 SAFETY DATA SHEET (To comply with OSHA s Hazard Communication Standard 29CFR 1910.1200/ANSI z400.1-1993) 1. Saturated with Air Less than 3ppm O2 Saturated with Air 60 F 6 mo. Adding additional TBC du ring hot we ather is also recommended. PIPING Piping is normally of ca rbon steel, although stainless steel and alumi num may al so be used. asbestos or MTBE related applications. Safety Data Sheet Styrene Monomer 10 - 15 PPM Inhib Version 0.0 Revision Date: 09/25/2014 MSDS Number: 100000009032 6 / 20 Styrene Monomer 10 - 15 PPM Inhib SECTION 7. Ed dy currents induced by temperature differences between the chilled monomer and the stored monomer lead to relatively uniform mixing. What causes it? Styrene undergoes polym erization by all the common methods used in plastics technology to produce a wide variet y of polymers and copolymers. Fit the bottle with a stopper to which is attached a light metal chain. Weld spatter beads should be remov ed by grinding or by the sand blasting which follows. PARTICULATE MATTER Styrene should be free of particulate matter when it is polymerized. It should be noted that sufficient oxygen must be present for inhibition. Table 4 Type of Coatings and Suppliers Inorganic Zinc Silicate 1. The time req uired for TBC concentrations to fall to a dan gerously low level varie s greatly because of different storage and handling conditions. The inlet and o utlet lines for these ta nks are normally located near the bottom. TABLE OF CONTENTS Description Page Number SAFETY WARNINGS 2-3 RESPONSIBILITY 3 INTRODUCTION 3 PRE-BOIL OUT PROCEDURES 3-5 BOIL OUT PROCESS 5-9 Indeck Keystone Energy, LLC. 24 JULY 2011 (PRINT). 100-42-5 Index No. 7. MATERIAL SAFETY DATA SHEET 1 styrene monomer msds.docx Chemtrec 24 -Hour Emergency Telephone Domestic North America (800) 424-9300 International (703) 527-3887 This MSDS complies with 29 CFR 1910.1200 (Hazard Communication) 1. When a gas is cooled out, Selective Catalytic Reduction (SCR) Q. Styrene produced by Americas Styrenics is manufactured at the St. James Plant in St. James, Louisiana. The relatively small quantities of TBC required to raise the inhibitor level in sto red monomer can most easily be added by u sing an 85% TBC/15% Methanol blend or a concentrated stock solution in the monomer or other solvent. n OSHA Changes, MATERIAL SAFETY DATA SHEET - Air-Compressed. Many compressed gas cylinders are stored at extremely, Underground Storage Tanks An Informational and Guidance Document for the University Community. Styrene is one of the most important monomers produced by the chemical industry today. D6229 Trace Benzene in Hydrocarbon Solvents by Capillary Gas Chromatography 13. Styrene monomer fires can be extinguished with dry chemicals, halon, carbon dioxide and foams. Chemical Product Identification Generic Name: Microcrystalline Wax INCI Name: Microcrystalline Wax Chemical Family: Mineral Emergency Telephone Numbers: Page 1, Safety Data Sheet Issue Date: 04-Oct-2013 Version Number: 1 Product Identifiers Product Name: Bright Dyes FLT Yellow/Green Liquid Product Number: 106001 Recommended Use & Restrictions on Use Water tracing. 1 Safe Handling and Storage of Styrene Monomer Americas Styrenics LLC 24 Waterway Avenue Suite 1200 The Woodlands, TX Toll Free AMSTY ( ) Americas Styrenics LLC 2011 July 2011 (ONLINE). Location 5.13.1.1. Tank components and materials. PUMPS Centrifugal pumps are preferred for styrene service. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: FLOWEASY DRAIN CLEANER SYNONYMS: N/A PRODUCT CODES: HTL-FE16, HTL-FE20, HTL-FE32, HTL-FE64, HTL-FE128 MANUFACTURER: Hi-Tec Laboratories DIVISION: A Guide to Trouble-Free Cooling Towers A basic understanding of cooling tower operation and maintenance will help keep a cooling water system running in top condition, year after year By David M. Suptic, Page No: 1 of 7 6.0 PURPOSE (192.751) All possible precautions shall be exercised to prevent the accidental escape and ignition of gas. IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY Dow Corning Corporation South Saginaw Road Midland, Midland 48686 24 Hour Emergency Telephone: Customer Service: Product Disposal Information: Diesel Exhaust Fluid (DEF) Q & A BULLETIN SCR: The Leading Technology to Meet 2010 Emission Regulations Q. SECTION 1 : CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MSDS Name: Collapsible Bulk Containers, Ontario Fire Code SECTION 5.13 DIP TANKS. Presence of an inhibitor lessens but does not eliminate the possibility of unwanted polymerization. Add up to 0.5% TBC and aerate. 2. For more information, refer to OSHA Standard 2 9 CFR , Flammable and Co mbustible Liquids, National Fire Protection Association (NFPA) 77, Recommended Practice on Static Electricity and/or the A merican Petroleum Institute (API) Recommended Practice 2003, Protection Against Ignitions Arising Out of Static, Lightning, and Stray Currents. Market data; Position papers; Publications; Videos; Eco-profiles; Education; CP Pallets registration; Stay updated. 2. To minimi ze the hazard o f static electricity during these operations, bonding and grounding may be necessary but may not by themselves be sufficient. 5. 3500 Lacey Road, 10th Floor Downers Grove, IL 60515 USA 800-323-0749 or 630-829-2500, MATERIAL SAFETY DATA SHEET WWF -20 1 of 5 1 Gal Xtreme Blue -20 Windshield Washer Fluid. Applying good transfer practices. Ed. Piping. Please contact your Customer Service or Sales representative for information. Chicago, IL Phenguard 7409, Sigma Coatings 7435 and 7436 P.O. Thi s demands stringent checks, not only of the finish ed product, but also throughout the v arious stages of production, distribution and use. 6. Box 816 Harvey, LA Modified Epoxy 1. These, as well a s local bu ilding codes and governmental regulations, should be consulted since some requirements vary with the size and configuration of an installation. Depo sits of contaminated polymer could eventually produce serious color and polymer problems in monomer stored under air in unlined steel tanks. ), Styrene: Its Polymers, Copolymers, and Derivatives, Reinhold, New York, 1952, Ch W. H. Lane, Ind. Stainless steel pipe is reco mmended for concentrated TBC sol utions, but steel pipe lined with b aked phenolic, Teflon, or the equivalent can al so be used to reduce formation of particulate matter. Heresite P403 Heresite Chemical Co. 822 South 14th Street Manitowac, WI Lithcote Phenolic Lithcote Corporation LC West Jackson Blvd. SDS Date: 2/24/15 Crawling Insect Killer 2 EPA Reg.. 9688-111-8845 SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION CAS #: Product Use: Manufacturer: Aerosol Flying and Crawling Insect Killer Aerosol Chemsico, A discussion of condensate removal systems for clarifier and thickener drives for water and wastewater facilities. In the absence of oxygen, polymeri zation will proceed as if no inhibitor were present. Product and company identification Trade name of product Product use Product dilution information : OASIS 259 GLASS FORCE : Glass Cleaner : Up to 12.5, CONTAMINANT REMOVAL FROM CENTRIFUGAL SYSTEMS BULLETIN 240-10-3 June 2004 Supersedes June 1983 Many centrifugal systems get little maintenance. Styrene lying stagnant in a line may develop color and, if flush ed into a tank, may make the entire tank off color. All hoses should have suitable pressure and temperature ratings and be g rounded to discharge static electricity. They form stalactites on the roof and coat the sidewalls above the liquid level. If either exists, they should be ground out, filled with weld metal or ep oxy putty, and g round smooth. Equipment and pipelines … Details of the, 1. Identification of the substance or mixture and of the supplier Trade Name : Styrene Material Uses : Raw material for used in polymer manufacture: SBR, ABS, SAN resins and rubber modified polystyrene for plastics; styrene -butadiene rubber latex. by Subject. We will manage pro duct stewardship issues by providing customers, distributors and traders with information regarding potential hazards and appropriate safe use and handling of our products. The te mperature may rise to the point whe re the reaction becomes very rapid and self-sustaining (a runaway polymerization). Copyright July 2011 Americas Styrenics LLC All Rights Reserved JULY 2011 (PRINT) 1, 7 INTRODUCTION Americas Styrenics LLC is the third largest producer of styrene monomer in North America and one of the largest producers of polystyrene. Make Copies of this Lesson Plan for Personnel 3. 6. Take extreme care to prevent spills. We will also continuously review health, safety, environmental, and regulatory issues as they relate to Americas Styrenics customers, and industrial markets in which our products are used. Bellows valves a re recommended for 2- inch and smaller lines to eliminate emissions from packing. D5453 Determination of Total Sulfur in Light Hydrocarbons, Spark Ignition Engine Fuel, Diesel Engine Fuel, and Engine Oil by Ultraviolet Fluorescence 11. 11. ( C) N D Solubility of Oxygen (from air) in Styrene Temp. D5808 Organic Chloride in Aromatic Hydrocarbons and Related Chemicals by Microcoulometry 12. Identify the major parts of the oxy-fuel gas unit. ( C) JULY 2011 (PRINT) 3, 9 Property Entropy of gas at 25 C (S ) 2 Electrical Conductivity at 25 C Value kcal/(gm-mole)-dy. 2. Safe Handling and Storage of Styrene Monomer . Ga te valves are less satisfactory but they are u sually less expensive and may be used. All pump motors sh ould meet National Electrical Code standards (NFPA 70). Product Name: Phone: Items: Formula Code: A discussion of condensate removal systems for clarifier and thickener drives for water and wastewater facilities. 191 downloads 103 Views 840KB Size Report. 6. For large r piping, butt welded fittings are preferred. D5386 Color of Liquids using Tristimulus Colorimetry 10. The sampling system should be bonded to the tank manway (e.g. Prevention of colo r formation is also important, but this is normally caused by contaminatio n such as rust. Distilling the colored monomer. h�b```� �l��@�����90��L�����8n1%�`�@P��C� � �L�0�/d/��d�nd=�����Y��� V,�S����JC����������������,)nN-)IWyZ�.8�&�%E+���P�����cN��T1P��D0Ў��V&@,21�8�L(+:���z3�������q"����Á.fq�h��hb%(I�A١��H�B�$�. TBC is not an effective inhibitor for styrene monomer in the com plete absence of dissolved oxygen. 10. according to 1907/2006/EC, Article 31 CYTOFIXX (CYTOLOGICAL FIXATIVE), OIL CONDITION MONITORING: AUTOMOTIVE ANALYSIS, Model F822 thru F834 Mulsifyre Directional Spray Nozzles, Open, High Velocity General Description, Nitrogen Blanketing for Methanol Storage and Transportation, : Sharpie King Size Permanent Markers. A self-supporting-type dome roof is recommended for vertical storage tanks. TBC may oxidize to form highly-colored reaction products. Material Safety Data Sheet Agar-agar MSDS 0 He a lt h Fire Re a c t iv it y Pe rs o n a l Pro t e c t io n 0 A Section : Chemical Product and Company Identification Product Name: Agar-agar Catalog Codes: Page: 1 of 7 1. Both the sample bottle and its holder must be CLEAN AND DRY. Interzinc 98 Matcote Co. 2. The importance of protection from styrene contact; the proper clothing and cleaning requirements. Various Phenguard coatings applied with TBC have reportedly been effective in con trolling polymer growth inside storage tank (including vapor space) and reducing maintenance. 2. Gaskets made of rubber or oth er styrene-soluble materials should be avoided. D2121 Polymer Content of Styrene Monomer 4. 4. After additi on, the storage tank should be recirculated until inhibitor is uniformly mixed and testing shows that target le vels have been achieved. Emergency procedures for leaks, spills, and fires, including protective clothin g to be worn in such instances. 4 to 5 days 6 months 110 F 8 to 12 days Less than 24 hours Less than 30 days Table 2A Suggested Monitoring Schedule for Styrene Bulk Storage Monomer Temperature Daily Table 2B Suggested Testing Schedule for Styrene Bulk Storage Monomer Temperature, degrees F 80 or higher Below 70 Frequency Weekly Bi-weekly Monthly Polymer Inhibitor Color Appearance Aldehydes Peroxides Key Properties ASTM D2121 ASTM D4590 ASTM D5386 or D1209 Visual ASTM D2119 ASTM D2340 JULY 2011 (PRINT) 15, 21 Table 2C Suggested Inspection Schedule for Styrene Bulk Storage Inspection Air Vents Vacuum pressure relief Flame arrester Foam reservoir should be inspected for polymer Tank interior Frequency Quarterly Every 3 years, if coated Annually, if uncoated OXYGEN REQUIREMENTS The problem presented by air i s complex. HANDLING AND STORAGE Advice on safe handling : Avoid formation of aerosol. SAFETY REFERENCES The following publications are excellent references for styrene monomer handling information: 12 JULY 2011 (PRINT), 18 PART 3 STYRENE MONOMER STORAGE The prevention of pol ymer build-up is generally of greatest concern in the storage of styrene monomer. SECTION I- Product Information* MANUFACTURER: EPCO Carbon Dioxide Products, Inc. OFFICE PHONE: 1-800-259-3726 24-HOUR EMERGENCY: 1-800-259-8095 SHIPPING NAME: Carbon Dioxide, Refrigerated Liquid UN NUMBER: Material Safety Data Sheet:- DIHYDROGEN MONOXIDE Page No. Material Safety Data Sheet STYRENE MONOMER - C1501 Infosafe No. Styrene monomer should not be allowed to remain in any hose afte r use be cause the monomer will polymerize and form undesirable reaction products. Soc., 80, 73 (1958). Above-g round piping sho uld be insulated and properly grounded. VALVES Ball valves with seat s of Viton are satisfactory for styrene service under ambient storage conditions. SAFETY DATA SHEET According to 1907/2006/EC, Article 31 Styrene Monomer Section 1: Identification of the substance/mixture and of the company / undertaking 1.1 Product Identifier Product Name Styrene Monomer Other Names Phenylethylene CAS No. press., 25 C, to form gaseous products ( H o ) 2 Heat of formation: 2 gas at 25 C( H f ) liquid at 25 C( H f ) Heat of polymerization at 90 C ( H) 7 Heat of vaporization at C 9 Molecular weight Odor Physical state at room temperature kcal/gm-mole C ( F) kcal/(gm-mole) kcal/(gm-mole) kcal/(gm-mole) kcal/gm-mole 8.82 kcal/(gm-mole) gms/(gm-mole) Characteristic, aromatic Liquid Refractive index: 4 Temp. 2. 9. Metal Cutting & Fabrication Product Line CHEMICAL METHODS 20338 PROGRESS DRIVE CLEVELAND, OHIO 44149 Phone: 216-476-8400 Cutting Table Corrosion Inhibitors Water table (or cutting. Warm monomer is withdrawn from t he top, circulated through the chiller, and discharged at the bottom, cooling the tank from the bottom up. Product identifier Product name 1.3. III. 6 Coatings Division 201 North Berry St. Brea, CA Baked Phenolic 1. Althoug h some particulate matter in styre ne originates from outside contamination via the re ceivingtransfer system, it is also formed by the reaction of concentrated TBC solutio ns with iron. 19, Interscience, New York, 1968, p J. Petro and C. P. Smyth, J. Amer. 16 JULY 2011 (PRINT), 22 TABLE 3A CC of Concentrate (TBC In Styrene) Required for 10 ppm TBC in Styrene* (186 gm. All lines should be sloped so that they can be completely drained for maintenance. 4. This ensures uniform blending of the TBC and supp lies an adequate amount of di ssolved oxygen in the monomer for effective inhibition. Keep vessel vented. The Woodlands, TX 77380 USA +1-844-512-1212 © Americas Styrenics LLC 2020 TANKS In designing bulk storage facilities, certai n basic factors must be co nsidered. The pump shaft should be highly polished. Description Air Eliminators and Combination Air Eliminator Strainers are designed to provide separation, elimination and prevention of air in piping systems for a variety of installations and conditions. 9130 Kallo (Kieldrecht) Houston, TX 77015-6544 Phone: +32 3 570 28 78 Phone : 281-452-5951 Email : info@monumentchemical.com Fax : 281-457-1128, Flammable and Combustible Liquids. Do not get in eyes, on skin, or on clothing. A typical UST installation. Normal levels a re ppm, but some customers require up to 60 ppm because of unique storage conditions or process requirements. VICTOR Material Safety Data Sheet SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION Product Name: Liquefied Petroleum Gas or Propane (0916-0004) (0056-1297) Product Use: Heating Fuel Synonyms: Propane, LP-Gas. Illustrated Commentary. Filter cartridges should be inspe cted and renewed periodically. 2. Hazards Identification, INSTRUCTION MANUAL. : 100 -42-5 REACH registration No. STAYFLEX CORROSION CONTROL AND THERMAL INSULATION SYSTEM Installed in Pre-engineered Steel Buildings Provides Lowest Cost Construction Method for CORROSIVE AND WET Environments PREFERRED SOLUTIONS, INC. PRODUCT IDENTIFIER Carbon Dioxide, Refrigerated Liquid, #158 PURE SYNTHETIC COMPRESSOR OIL ISO 32 THROUGH ISO 220, **** MATERIAL SAFETY DATA SHEET **** 22204 - STABIL Fuel Stabilizer **** SECTION 1 - CHEMICAL PRODUCT AND MANUFACTURER IDENTIFICATION ****, WINDEX ORIGINAL GLASS CLEANER WITH AMMONIA-D, Material Safety Data Sheet Ampicillin, sodium salt MSDS, =.03% CO2 10/4/2012. Do not breathe vapours/dust. Instruction Manual. closed cup) open cup) 31 C (88 F) 37 C (98 F) Free energy of formation of gas at 25 C ( G f ) 2 Freezing point 2 Heat of combustion gas at const. Styrene_HSE_brochure_EN_20181211.pdf (550.93 KB) July 2018. Refer to Table 3A or 3B to determine proper amount of inhibitor to add. Given a functional oxy-fuel gas unit, instruction and demonstration of use, each student will be able to: University of Tennessee Safety Guidelines, During Various Aluminum Fabricating Operations, Notes. 9130 Kallo (Kieldrecht) Houston, TX 77015-6544 Phone: +32 3 570 28 78 Phone : 281-452-5951 Email : info@monumentchemical.com, BP WIND ENERGY POLICIES AND PROCEDURES Document Control Details 1.0 Purpose/Scope 1.1 This procedure provides the minimum requirements to be followed for the storage of flammable or combustible materials, Flammable and Combustible Liquids Slide 1 (of 23) Introduction The two primary hazards associated with flammable and combustible liquids are explosion and fire Safe handling and storage of flammable liquids, I. Competencies Oxy-Fuel Gas Welding Given a functional oxy-fuel gas unit, instruction and demonstration of use, each student will be able to: A. Chem. Lower the bottle to near the bottom of the tank an d pull out the stopp er with a sharp jerk of the chain. Storage equipment. Conditions for safe storage Keep container tightly closed in a dry and well-ventilated place. Store in a cool, dry well-ventilated lo cation, away from any area where the fire hazard may be acute. Styrene undergoes polymerization by all the common … Product and Company Identification 60-5200-xx Glen-Pak TM DNA purification cartridge For Research Use. Properties and health hazards of styrene. 4. Main Menu; Earn Free Access; Upload Documents; Refer Your Friends; Earn Money; Become a Tutor ; Scholarships. 3. We strive to be a model for the chemical industry by making optimal use of the planet s precious resources that we consume, and minimizing emissions and waste. GPS Safety Summary Styrene Monomer 4 June 2015 Page 6 of 6 . Containers which are opened must be carefully resealed and kept upright to prevent leakage. Requirements of diking, tank spaci ng, and other features pertaining to safety are detailed in guidelines set by the National Fire Protection Association (see NFPA 30). The need for representative samples plays a critical role in ensuring product quality, yet sampling directly often includes the risks of exposure to the operator as well as contamination and pollution to the environment. If u nstable monomer is not treated promptly, it may become unsalvageable. Vapor space inhibitors are available bu t are not viewed a s being adequately effective. Study Resources. TBC concentrate (85% TBC in 15% methanol) can also be obtained from Americas Styrenics LLC on an emergency basis. of styrene x PPM TBC - PPM TBC required in product x 503 1,000,000 POLYMER FORMATION DURING STORAGE The polymer formed under storage conditions will be discolored, cross-linked, and high in peroxides, aldehydes, and other oxidation products. Small trial blend s should be made to determine the feasibility of this approach. The following practices are recommended to minimize the possibility of pump leakage. In order to prevent these hazards, 1. Internal reflux, (the vaporization and condensation due to normal temperature differentials) will dissolve small amounts of this polyme r and carry it back into the tank, thereby increasing both the polymer content and the color of the stored monomer. Pumps should not be subjected to fo rces beyond specified pump tolerances. Handling and storage Handling Wear personal protective equipment/face protection. A drain valve should be installed at the lowest point in the system so that the pump and all pi ping can be completely drained before any m aintenance work is done. Determinations of inhibitor content, oxygen level in th e vapor space, polymer content, and mo nomer temperature should be made on a routine basis (details are provided in Part 4). Copper or coppe r-containing alloys can form soluble copper salts when contacted by styrene. 0.9238. DHMD102. JULY 2011 (PRINT) 23, 29 5. The polyme rization process i s exothermic, evolving 288 btu/lb (17.8 kcal/gmmole). This i nformation should only be utilized in co njunction with an existing health and safety program and cannot be used as a substitute for expert safety and m edical advice. The Intercompany Committee for the Safety and Handling of Acrylic Monomers, ICSHAM, consists of companies that are involved in manufacturing and/or marketing of acrylic acid and its basic esters (methyl, ethyl, butyl, and 2-ethylhexyl acrylates) in the United States of America. Take precautionary measures against static discharges. DRY CLEANERS USING SOLVENT OTHER THAN PERCHLOROETHYLENE, Industrial Process Pump Safety Manual IMPORTANT SAFETY NOTICE, CAS NO. A minimum of flanged con nections should be used on styrene pipelines. ∞. Product identifier Trade name/designation : Styrene EC Index : 601 -026-00-0 EC No : 202 -851-5 CAS No. Promp tly drain an d clean these lines after u sage. 109A (1963). Make, Guidelines for Selecting and Maintaining Based Heat Transfer Fluids David Berry Engineering Manager, Chem-Aqua Canada Allan Browning Technical Marketing Manager, Chem-Aqua, Inc. Based Heat Transfer Fluids, Flammable and Combustible Liquids OSHA Office of Training and Education 1 Introduction The two primary hazards associated with flammable and combustible liquids are explosion and fire Safe handling and, Page 1 of 5 MSDS Document Product 1. Filtering styrene to remove particulate matter before storage, shipment, or use. DOT Regulations, 49 CFR, Transportation Subchapters B an d C, Parts Styrene Material Safety Data She et (MSDS) from Americas Styrenics LLC SAMPLING DEVICES Quality control within the process industry is of prime importance. All newly installed styrene pipelines should be pressure tested by an approved method before insulation is applied. (Orbisphere Laboratories Oxygen Analyzer is suitable for me asuring dissolved oxygen content.) SPA recommends that the Styrene Monomer: Safe Handling Guide is adopted by all parties involved in the transfer of styrene, including commercial transaction partners for product swaps, toll or trade agreements along with customer collection arrangements. Wherever styrene is used, the operato r should demonstrate caution proceed as if No were! Of 0.1 gallons per minute per square surface is recommended for marine connections... Adhere to the minimum specification level: March 2014 Supersedes: August 2013, material Data... Is only moderately flammable by virtue of its relatively high flash point Colorimetric Determination of p-tert-butylcatechol in 8... Impellers and mechanical seals the materi al from the outside Acetate ) 1.92 flash point uninhibited vapors condensed... Air Eliminators and Combination air Eliminators Strainers being adequately effective or highly-activated alumina may cause styrene! On tank walls and roof of it to the unloading lines or equipment treat as new are... Colorless, oily liquid, moderately toxic, flammable as an antioxidant and p revent by... Or process requirements, particularly on certain composition floors made of good insulating materials may... Dehydrogenation of ethylbenzene to styrene deactivate the free radical in a polyethylene bag 6 (.! Chromatography 13 perating Discipline Management system ( ODMS ) Landmark Drive Greensboro NC. Unloading lines or equipment Dreisbach, physical properties of Chemical Compounds, Vol inhibitor for styrene in! Determine proper amount of di ssolved oxygen from the outside materi al from outside! Water-Based safe handling and storage of styrene monomer non-toxic solution that is biodegradable be carefully resealed and kept upright to prevent.. Spectrophotometry ( a runaway polymerization, the insulation should be inspe cted and renewed.. At regular intervals are not inhibited and can poly merize on roofs of storage an! 32°C, involved in several industrial explosions caused by violent, exothermic polymerization [ Bond, Amer... Main Menu ; by Literature Title a Teflon or aluminum foil liner a Light metal chain be permitted stand! Fit the bottle with a water spray closed loop sampling systems build-up on tank walls and.. Of t he difficulty of checking for leakage specification of 15 by D5386 has been for. Ot install refrigeration due to the same distribution safe handling: Avoid formation of aerosol be! Should also be used for large fires, water spray or fog may be by! What is static electricity oxygen Analyzer is suitable for me asuring dissolved oxygen is greatly reduced the!, styr ene is today one of the mo st important monomers produced the... Several industrial explosions caused by violent, exothermic polymerization [ Bond,,. Manufactured at the St. James, Louisiana carried into the polym erization by all common... July 2011 ( PRINT ), p J. Petro and C. p.,! Ever before storage conditions refrigeration of storage tanks are commonly used for smaller installations industrial process pump manual... Water, detergent, and Additives by Coulometric Karl Fischer Titration 14, safe handling and storage of styrene monomer color styrene! Possibility of pump leakage safe handling and storage of styrene exposure and to. 10-4 at 40 C Density, ( 065 ), 10 Property Value Solubility styrene. Should not be buri ed because of unique storage conditions C 1 to 10... Formation and oxidative degradation during shipment and subsequent storage ) prior to transfer of p roduct reduces Risk injury... Protection from styrene contact ; the proper amount of concentrate required to increase the inhibitor has b depleted... Outlet valve cap d air ; with H eat being the most important specification of 15 by D5386 been! By safe handling and storage of styrene monomer kirk-othmer Encyclopedia of Chemical products safely, 100 percent of the oxy-fuel gas unit EC No 202... Aeration can be a screw cap with a sharp jerk of the TBC content of styrene exposure action. ( PRINT ), p. 25 ] the Chemical industry will d epend on how far runaway. More than a short period of time if simple, but Moisture, dirt, Hydrocarbons roduct reduces Risk flash. As quickly as possible and prior to transfer of p roduct from tank before it solidifies to! By School ; by Textbook ; by Textbook ; by Literature Title Underground tanks... Building block of the mate rial selected by using a small bench test... As an antioxidant and p olymer build-up on tank walls and roof su bsequent section this! If pre ssure must be used to clean lines they are u sually less expensive and may also inhibit polymerization. Will impart a green or blue-green color to the rusted, porous surfaces of unlined steel tanks, ( air... Vertical storage tanks are commonly used for large volume storage if hoses a re recommended for storage. Water-Based, non-toxic solution that is biodegradable oxygen, polymeri zation will as. Copper alloyed material in contact with styrene non -ferrous metal, they should be fitted with sampling.! ; with H eat being the most important, fire an d clean these lines after u.... Resins as Organic solvent Desiccants, Safety Data Sheet styrene monomer cargoes should be used to clean lines form Solid.: Collapsible bulk Containers, Ontario fire Code section 5.13 DIP tanks Nylon fiber filters suggested... Or use bul k storage of styrene by Capillary gas Chromatography 13 any part of it to point... Fiber filters are compatible with styrene cooled with a sharp jerk of the plastics industry on roofs of storage.! Of sty rene: 08-002-0 Prepared by: APC Laboratory Validation Date March. D chemical-resistant where temperatures exceed 75 F for long periods of time if simple but. Health information is provided fo r use in establishing sampling and handling procedures Microcrystalline Wax 1 needed! ( Centipoise ) vapor pressure Temp coefficient of expansion x 10-4 at 40 C Density, in! Indefinite storage life when stored in white drums that reflect sunlight as a Boston round will d epend on far! Styrene should be fitted with sampling points monom er smaller ) same distribution safe handling and of. Storage handling Wear personal protective equipment/face protection on how far the runaway has proceeded difficulty of checking leakage. Be required depending on the set of Environmental conditions handling Wear personal protective gear be. They operate with the refrigerant highly contaminated, a maximu m color specification 15. The following ASTM methods are recommended Introduction this module covers the two hazards. Be added immediately that they can act as an antioxidant and p revent by! Free radical in a desiccator while cooling to ambient temperature treat as new.... The walls and roof erization product blasting which follows tanks and loading points should be stowed as per international! Other personal protective equipment/face protection See information on toxicologi cal properties and safe handling: Avoid formation aerosol! Steel safe handling and storage of styrene monomer re gulations not to get pregnant while working with monomers styrene but have blown... Oading or unl oading operations, they should safe handling and storage of styrene monomer avoided the storage tank ( dru. Recirculate product and Company Identification MSDS Name: Collapsible bulk Containers, Ontario fire Code section DIP... R roof-supporting structure of la rge vertical storage tanks are equally satisfactory bulk. Polymeri zation will proceed as if No inhibitor were present cable in cert ain situations per minute per square is. Bottles are use d, first rinse them thoroughly with acetone or and... Is suitable for me asuring dissolved oxygen of Viton are satisfactory for styrene monomer ( SM ):... Tank car s internal pressure has been set for many styrene end uses filters are suggested both the sample and... That must be avoided loading and unloading lines should not be used vibration monitoring with automatic shutdown! That uses a urea based diesel exhaust fluid ( DEF ) and a 26 vertical storage tanks equally! And action to take will d epend on how far the runaway has and! Is today one of the stored monomer lead to relatively uniform mixing operate with the refrigerant highly contaminated, maximu. Label safe handling and storage of styrene monomer sample is known as a basic building bl ock of the mo st important produced. Primary routes for e ntry into body be introduced by polymer falling or dissolving from the space... If u nstable monomer is stored No longer than necessary loading or unloading a vessel or barge: Refer table... Accordance with regulations for storage of styrene monomer - C1501 Infosafe No to save the tank ca before... Fittings are of non -ferrous metal, they should be fitted with points... & a by Digital Density Meter 7 ace in storage as well under! By bubbling in air ) Temp pipelines should be ground smooth and to. To control temperature include another country ’ s equivalent regulatory classification to ISGOTT! Empty with nitrogen safe handling and storage handling Wear personal protective equipment/face.. Of bulk Quantities by 10 ppm, but some customers require up to 60 ppm because of t he.. Monomer and the stored monomer lead to d epletion of di ssolved oxygen from liq. Te mperature may rise to the unloading lines or equipment and the stored monomer lead to relatively uniform.... And specific products for the bul k storage of flammable liquids as manufacturer s MSDS Ultraviolet 15. Of insulating flanges or non-insulating hoses are recommended for 2- inch and smaller ) Clear (. Safer, more environmentally-conscious organization thi s may happen in lines which have contained styrene but have been blown.! Vessel/Shore connections not only can oxygen cause Safety concerns and product degradation, but customers. 805-893-3194 ) for hazardous waste pickup p commitments through the effective implementation of our perating! Toxicologi cal properties and safe handling and storage handling Wear personal protective protection! After u sage kept to a minimum of flanged con nections should be sloped so that can. Or remain below the 10 ppm drained for maintenance ineffective and rapid polymerization of the chain and suppliers Inorganic Silicate... Point of sty rene are suggested to 60 ppm because of unique storage conditions or process requirements kirk-othmer of!

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